Synthesis Gas and Zinc Production in a Noncatalytic Packed‐Bed Reactor

A noncatalytic packed‐bed reactor has been constructed for management of the reduction of ZnO by methane, which leads to co‐production of synthesis gas and zinc. The reactor consisted of a simple vertical pipe filled with ZnO pellets. These pellets underwent reaction with a pure methane flow. Experimental tests were conducted in the temperature range 860–995 °C at atmospheric pressure in an electrically heated reactor. The results showed complete chemical conversion of methane to synthesis gas in the aforementioned temperature range. In addition, analysis of the product solids indicated that the collected solids in the outlet of the reactor were entirely zinc. The maximum methane flow rates (149–744 mL min^–1) were adjusted to ensure complete chemical conversion of methane. These adjustments were performed for different bed heights at various operating temperatures. Analysis of the product gases revealed high quality synthesis gas production without the influence of methane cracking or other undesired side reactions in the experimental tests. Finally, the governing partial differential equations of the reactor modeling were solved by the finite element method. Consequently, the gaseous profiles along the reactor and the breakthrough curves were predicted and compared with the experimental tests.     

The improved electrocatalytic activity of palladium/graphene nanosheets towards ethanol oxidation by tin oxide

Tin oxide (SnO₂)/graphene nanosheets (GNS) composite was prepared by a simple chemical-solution method as the catalyst support for direct ethanol fuel cells. Then the SnO₂-GNS composites supporting Pd (Pd/SnO₂-GNS) catalysts were synthesized by a microwave-assisted reduction process. The Pd/SnO₂-GNS catalysts were characterized by using X-ray diffraction, transmission electron microscopy and energy-dispersive spectroscopy techniques. The electrocatalytic performances of Pd/SnO₂-GNS catalysts for ethanol oxidation were studied by cyclic voltammetric and chronoamperometric measurements. It was found that compared with Pd/GNS, the Pd/SnO₂-GNS catalyst showed superior electrocatalytic activity for ethanol oxidation when the mass ratio of SnCl₂·2H₂O precursor salt to graphite oxide was about 1:2.     

SYNERGISTIC EFFECTS OF ANIONIC SURFACTANT AND NONIONIC POLYMER ADDITIVES ON DRAG REDUCTION

Turbulent drag reduction (DR) behavior of mixed nonionic polymer and anionic surfactant solutions in water was studied in a pipeline set up to explore the synergic effects of mixed additives on DR. The concentration of polymer polyethylene oxide (PEO) was varied from 0 to 2000 ppm and the concentration of surfactant sodium dodecyl sulfate (SDS) was varied from 0 to 5000 ppm. The critical aggregation concentration (CAC), where the interaction between the polymer and the surfactant begins, and the polymer saturation point (PSP), where the polymer molecules become saturated with the surfactant, were determined using electrical conductivity and surface tension measurements. As the polymer concentration was increased the CAC decreased but the PSP increased. The relative viscosity showed a remarkable increase upon the addition of surfactant to the polymer solution due to extension of polymer chains caused by the formation of micelles on the backbone of the polymer molecules. The data exhibited a considerable increase in DR in the case of mixed polymer/surfactant systems. The percent reduction in friction factor was as high as 79 when 3000 ppm or more surfactant was added to the 500 ppm polymer solution. Furthermore, the drag reduction behavior of the polymer solution changed from so-called Type A to Type B. In Type A drag reduction, a transition from laminar to turbulent regime is observed with a clear-cut onset point. In Type B drag reduction, no transition or onset point is observed; the data fall on a gradual extension of the laminar line.     

Reduction of fractures in dried clay-like materials due to specific surfactants

The possibility of fracture reduction as a result of application of specific surfactants during intensive drying of clay-like materials was examined in this paper. The dodecyl sulfate sodium salt (SDS) and the fluoric (FC 4430) surfactants were used for the tests. Different amounts of these surfactants were mixed with distilled water and used for wetting a dry clay material before forming clay samples. The clay samples in the form of cylinders 44 mm in diameter and 50 mm high were extruded and after leveling the moisture distribution subjected to convectively drying in hot air at 120 °C. The acoustic emission (AE) method was used to monitor on line the development of crack formation in dried samples. It was stated that application of surfactants in a prescribed amount may significantly reduce the drying induced fractures in clay during its intensive drying and thus to obtain good quality products by high drying rates.     

集中供暖换热站扩容供热方式的选择

通过对某换热站新增区域的供热方式与原采暖用户进行系统分析,建议新增区采用间接连接和混水直接连接两种方案,并对两种方案给出详细的设计说明;通过对两种方案进行整体比较分析,综合得出混水直供换热方式运行经济,供热效果良好,尤其是区域供热新增区或新建区采暖用户的供热选择方式。     

大客车主减速器改造对节能减排的作用

针对汽车尾气排放对城市空气造成严重污染的现实情况,对在用公交大客车进行技术改造以达到节能减排效果的方法进行了研究和尝试。其重点是通过对大客车传动系统的关键部件进行改进,以最大限度发挥汽车发动机的动力性能,从而达到节能减排的目的。经过实践证明,该项技术改造投入少,见效快,节能减排效果明显,推广应用将对企业带来良好的经济效益和社会效益。     

Evaluation of combined heat and power (CHP) systems performance with dual power generation units for different building configurations

This paper evaluates the economic, energetic, and environmental feasibility of using two power generation units (PGUs) to operate a combined heat and power (CHP) system. Several benchmark buildings developed by the Department of Energy simulated using the weather data for Chicago, IL, are used to analyze the proposed configuration. This location has been selected because it usually provides favorable CHP system conditions in terms of cost and emission reduction. For the proposed configuration, one PGU is operated at base load to satisfy part of the electricity building requirements, whereas the other is used to satisfy the remaining electricity requirement operating following the electric load. The dual‐PGU CHP configuration (D‐CHP) is modeled for four different scenarios to determine the optimum operating range for the selected benchmark buildings. The dual‐PGU scenario is compared with the reference building using conventional technology to determine the benefits of this proposed system in terms of operational cost, primary energy reduction, and carbon dioxide emissions. The D‐CHP system results are also compared with a CHP system operating following the electric load (FEL) and base‐loaded CHP system. For three of the selected buildings, the proposed D‐CHP system provides comparable or greater savings in operating cost, primary energy consumption, and carbon dioxide emissions than the optimized conditions for base loading and FEL. In addition, the effect of operating the D‐CHP system only during certain months of the year on the overall operational cost is also evaluated. Results indicate that not operating the D‐CHP system for the months where the thermal load is too low is beneficial for the overall system performance. Copyright © 2012 John Wiley & Sons, Ltd.     

Characteristic study,its identification and self-tuned approach to control hydro-power plants

The water time constant and mechanical time constant greatly influences the power and speed oscillations of hydro-turbine-generator unit. This paper discusses the turbine power transients in response to different nature and changes in the gate position. The work presented here analyses the characteristics of hydraulic system with an emphasis on changes in the above time constants. The simulation study is based on mathematical first-, second-, third- and fourth-order transfer function models. The study is further extended to identify discrete time-domain models and their characteristic representation without noise and with noise content of 10 & 20 dB signal-to-noise ratio (SNR). The use of self-tuned control approach in minimising the speed deviation under plant parameter changes and disturbances is also discussed.     

Adsorption and reduction of platinum(IV) chloride complex ions on activated carbon

The adsorption kinetics of platinum(IV) chloride complex ions on the activated carbon Norit GF40 was investigated. Experiments were carried out at different initial concentrations of Pt(IV) chloride complex ions, temperature, rate of mixing and pH. It was found that the value of activation energy of the studied process is equal to 19.7 kJ/mol. From the ICP MS analysis it was confirmed that platinum ions (Pt(IV) and Pt(II)) are removed from the solution due to the adsorption and are further reduced to the metallic state. Such mechanism was confirmed by XPS analysis which showed that on the carbon surface three forms of platinum species, i.e. Pt(0), Pt(II) and Pt(IV), exist. The presence of platinum in the solution at different oxidation states was also confirmed spectrophotometrically by identification of their characteristic absorption bands. The metallic form of Pt present on the surface of activated carbon was observed in the form of small spherical islands with the diameter not exceeding 500 nm. Those islands consist of smaller, flake-shape particles with a thickness of about 35 nm.